Cyclic carbonates synthesis from epoxides and CO2 over NIIC-10 metal-organic frameworks

被引：24
|
作者：
Bondarenko, Grigoriy N. [1 ]
Ganina, Olga G. [1 ]
Lysova, Anna A. [2 ]
Fedin, Vladimir P. [2 ]
Beletskaya, Irina P. [1 ]
机构：
[1] Lomonosov Moscow State Univ, Dept Chem, 1 Leninskie Gory,GSP-2, Moscow 119992, Russia
[2] Russian Acad Sci, Nikolaev Inst Inorgan Chem, Siberian Branch, Novosibirsk 630090, Russia
来源：
JOURNAL OF CO2 UTILIZATION | 2021年 / 53卷
基金：
俄罗斯基础研究基金会;
关键词：
Metal-organic frameworks; Epoxide; Carboxylation; CO2; conversion; Zn-complex; CATALYZED CARBOXYLATION; CHEMICAL FIXATION; ZN-MOF; DIOXIDE; CONVERSION; ADSORPTION; MILD; DFT;
D O I：
10.1016/j.jcou.2021.101718
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
A series of microporous metal-organic frameworks, NIIC-10, based on 2,5-thiophendicarboxylate (tdc(2-)), 1,4-dia-zabicyclo [2.2.2] octane (dabco), polyol ligands and Zn-ions were investigated in carboxylation of mono-, di and tri-substituted epoxides in the presence of tetrabuthylammonium bromide (TBAB). Reactions were carried out in solventless media under CO2 atmosphere and 80 degrees C. All resulting mono- and disubstituted cyclic carbonates were obtained in good to excellent yields. Furthermore, the catalyst also showed good selectivity and recyclability for five cycles without a significant loss of activity.
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页数：8
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