Sustainable Development of Palm Oil: Synthesis and Electro-chemical Performance of Corrosion Inhibitors

被引:32
|
作者
Porcayo-Calderon, J. [1 ,2 ]
Rivera-Munoz, E. M. [3 ]
Peza-Ledesma, C. [3 ]
Casales-Diaz, M. [1 ]
Martinez de la Escalera, L. M. [4 ]
Canto, J. [4 ]
Martinez-Gomez, L. [1 ,4 ]
机构
[1] Univ Nacl Autonoma Mexico, Inst Ciencias Fis, Av Univ S-N, Cuernavaca, Morelos, Mexico
[2] Univ Autonoma Estado Morelos, CIICAp, Av Univ 1001, Cuernavaca 62209, Morelos, Mexico
[3] Univ Nacl Autonoma Mexico, Ctr Fis Aplicada & Tecnol Avanzada, Campus Juriquilla, Queretaro, Qro, Mexico
[4] Corros & Protecc, Buffon 46, Mexico City 11590, DF, Mexico
关键词
Palm oil; Sustainable development; Corrosion inhibitor; Fatty amides; Electrochemical techniques; CARBON-STEEL; PIPELINE STEEL; MILD-STEEL; BEHAVIOR; SURFACTANTS; BIODIESEL; ALLOYS; COPPER; IRON;
D O I
10.33961/JECST.2017.8.2.133
中图分类号
O646 [电化学、电解、磁化学];
学科分类号
081704 ;
摘要
Palm oil production is among the highest worldwide, and it has been mainly used in the food industry and other commodities. Currently, a lot of palm oil production has been destined for the synthesis of biodiesel; however, its use in applications other than the food industry has been questioned. Thereby for a sustainable development, in this paper the use of palm oil of low quality for corrosion inhibitors synthesis is proposed. The performance of the synthesized inhibitors was evaluated by using electrochemical techniques such as open circuit potential measurements, linear polarization resistance and electrochemical impedance spectroscopy. The results indicate that the fatty amides from palm oil are excellent corrosion inhibitors with protection efficiencies greater than 98%. Fatty amides molecules act as cathodic inhibitors decreasing the anodic dissolution of iron. When fatty amides are added, a rapid decrease in the corrosion rate occurs due to the rapid formation of a molecular film onto carbon steel surface. During the adsorption process of the inhibitor a self- organization of the hydrocarbon chains takes place forming a tightly packed hydrophobic film. These results demonstrate that the use of palm oil for the production of green inhibitors promises to be an excellent alternative for a sustainable use of the palm oil production.
引用
收藏
页码:133 / 145
页数:13
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