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New Type of Organic Sensitizers with a Planar Amine Unit for Efficient Dye-Sensitized Solar Cells
被引:94
|作者:
Do, Kwangseok
[1
]
Kim, Duckhyun
[1
]
Cho, Nara
[1
]
Paek, Sanghyun
[1
]
Song, Kihyung
[2
]
Ko, Jaejung
[1
]
机构:
[1] Korea Univ, Dept Adv Mat Chem, Jochiwon 339700, Chungnam, South Korea
[2] Korea Natl Univ Educ, Dept Chem Educ, Cheongwon 363791, Chungbuk, South Korea
基金:
新加坡国家研究基金会;
关键词:
HIGHLY-EFFICIENT;
CYANINE DYES;
TETRAHYDROQUINOLINE DYES;
SPECTRAL SENSITIZATION;
CONVERSION EFFICIENCY;
MEROCYANINE DYES;
TRIANGULENE-TYPE;
COUMARIN DYES;
TIO2;
FILMS;
THIOPHENE;
D O I:
10.1021/ol203012s
中图分类号:
O62 [有机化学];
学科分类号:
070303 ;
081704 ;
摘要:
A new type of organic sensitizers incorporating a planar amine unit have been synthesized and demonstrated to be a highly efficient sensitizers, showing evidence of lateral interactions on the TiO2 surface. Under standard global air mass 1.5 solar conditions, the JK-98 sensitized cell gave a short circuit photocurrent density (J(sc)) of 16.78 mA cm(-2), an open-circuit voltage (V,,c) of 0.745 (V-oc) and a fill factor (ft) of 0.70, corresponding to an overall conversion efficiency (eta) of 8.71%.
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页码:222 / 225
页数:4
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