Alternative approach to an AB2 monomer for hyperbranched poly(arylene ether ketone imide)s

被引：6
|
作者：
Yu, Zhenning [1 ]
Fossum, Eric
Wang, David H. [2 ]
Tan, Loon-Seng [3 ]
机构：
[1] Wright State Univ, Dept Chem, Dayton, OH 45435 USA
[2] Univ Dayton, Res Inst, Dayton, OH 45469 USA
[3] USAF, Res Lab, Mfg Technol Directorate, Polymer Branch,Mat & Mfg Directorate,MLBP, Dayton, OH USA
来源：
SYNTHETIC COMMUNICATIONS | 2008年 / 38卷 / 03期
关键词：
branched polymer; monomers; selectivity;
D O I：
10.1080/00397910701771157
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
An alternative approach to an AB(2) monomer, N-[3,5-bis(4-hydroxybenzoyl)benzene]-4-fluorophthalimde, 4, for hyperbranched poly(arylene ether ketone imide)s has been developed. The key steps were a para-position selective electrophilic aromatic substitution of fluorobenzene with 5-nitroisophthaloyl dichloride and a subsequent clean conversion of the aryl fluorides to phenol groups using potassium hydroxide as the nucleophile. The overall yield for the synthesis of 4 was 51.6%.
引用
收藏
页码：419 / 427
页数：9
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