New (S)-proline derivatives as catalysts for the enantioselective aldol reaction

被引：5
|
作者：
Maleev, V. I. [1 ]
Gugkaeva, Z. T. [1 ]
Moskalenko, M. A. [1 ]
Tsaloev, A. T. [1 ]
Lyssenko, K. A. [1 ]
机构：
[1] Russian Acad Sci, AN Nesmeyanov Organoelement Cpds Inst, Moscow 119991, Russia
来源：
RUSSIAN CHEMICAL BULLETIN | 2009年 / 58卷 / 09期
关键词：
organocatalysis; asymmetric synthesis; aldol reaction; (S)-proline; ORGANOCATALYST; PROLINAMIDE; ALDEHYDES; KETONES; WATER;
D O I：
10.1007/s11172-009-0259-0
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
(2S)-N-{2-[(R)-Hydroxy(phenyl) methyl]phenyl}pyrrolidine-2-carboxamide, (2S)-N-{2-[(S)-hydroxy(phenyl)methyl]phenyl}pyrrolidine-2-carboxamide, and (S)-N-{2-[hydroxy-(diphenyl)methyl]phenyl}pyrrolidine-2-carboxamide were obtained and tested as catalysts for an asymmetric aldol reaction of 4-nitrobenzaldehyde with acetone.
引用
收藏
页码：1903 / 1907
页数：5
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