Preparation and characterization of some cobalt(III) complexes of 2-aminomethylbenzimidazole

被引:13
|
作者
Gable, RW [1 ]
Hartshorn, RM [1 ]
McFadyen, WD [1 ]
Nunno, L [1 ]
机构
[1] UNIV MELBOURNE,SCH CHEM,PARKVILLE,VIC 3052,AUSTRALIA
关键词
D O I
10.1071/CH9960625
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
The coordination chemistry of 2-aminomethylbenzimidazole (ambi) has been studied with cobalt(III), and the cationic complexes fac-[Co(ambi)(3)](3+), asym-[Co(en)(ambi)(2)](3+) and [Co(en)(2)(ambi)](3+) have been prepared. The last cation, in the form of the chloride salt [Co(en)(2)(ambi)] Cl-3.H2O, has been structurally characterized: monoclinic, space group P2(1)/c, a 7 . 6692(14), b 14 . 954(2), c 15 . 941(3) Angstrom,beta 92 . 64(2)degrees, Z 4.
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页码:625 / 632
页数:8
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