Preparation and characterization of some cobalt(III) complexes of 2-aminomethylbenzimidazole

被引：13
|
作者：
Gable, RW [1 ]
Hartshorn, RM [1 ]
McFadyen, WD [1 ]
Nunno, L [1 ]
机构：
[1] UNIV MELBOURNE,SCH CHEM,PARKVILLE,VIC 3052,AUSTRALIA
来源：
AUSTRALIAN JOURNAL OF CHEMISTRY | 1996年 / 49卷 / 05期
关键词：
D O I：
10.1071/CH9960625
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
The coordination chemistry of 2-aminomethylbenzimidazole (ambi) has been studied with cobalt(III), and the cationic complexes fac-[Co(ambi)(3)](3+), asym-[Co(en)(ambi)(2)](3+) and [Co(en)(2)(ambi)](3+) have been prepared. The last cation, in the form of the chloride salt [Co(en)(2)(ambi)] Cl-3.H2O, has been structurally characterized: monoclinic, space group P2(1)/c, a 7 . 6692(14), b 14 . 954(2), c 15 . 941(3) Angstrom,beta 92 . 64(2)degrees, Z 4.
引用
收藏
页码：625 / 632
页数：8
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