Phosphoric acid diesters as efficient catalysts for hydroaminations of nonactivated alkenes and an application to asymmetric hydroaminations

被引：53
|
作者：
Ackermann, Lutz [1 ]
Altharnmer, Andreas [1 ]
机构：
[1] Univ Gottingen, Inst Organ & Biomol Chem, D-37077 Gottingen, Germany
来源：
SYNLETT | 2008年 / 07期
关键词：
alkenes; amines; asymmetric catalysis; Bronsted acids; phosphates;
D O I：
10.1055/s-2008-1072505
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
Catalytic amounts of phosphoric acid diesters enabled highly efficient intramolecular hydroaminations of nonactivated alkenes. With an enantiomerically enriched Bronsted acid catalyst an unprecedented metal-free asymmetric hydroamination of a nonactivated alkene was accomplished.
引用
收藏
页码：995 / 998
页数：4
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