Polar BaCl(ClO4) • H2O layered chloride perchlorate

被引：4

作者：

Charkin, D. O. ^{[1
]}

Nazarchuk, E. V. ^{[2
]}

Stefanovich, S. Yu. ^{[1
]}

Djangurazov, E. B. ^{[1
]}

Zadoya, A. I. ^{[2
]}

Siidra, O. I. ^{[2
]}

机构：

[1] Moscow MV Lomonosov State Univ, Dept Chem, Leninskie Gory 1, Moscow 119991, Russia

[2] St Petersburg State Univ, Dept Crystallog, Univ Emb 7-9, St Petersburg 199034, Russia

来源：

INORGANIC CHEMISTRY COMMUNICATIONS | 2017年 / 84卷

关键词：

Polar compounds; Perchlorate; Chloride; Anion-centered tetrahedra; Single crystal X-ray diffraction; CRYSTAL-STRUCTURE; VIBRATIONAL-SPECTRA; SULFATES; POTASSIUM; LA; CE; LN;

D O I：

10.1016/j.inoche.2017.08.022

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Synthesis and crystal structure of a polar layered chloride perchlorate, BaCl(ClO4)center dot H2O (1) where the chlorine atoms play two crystallographically different roles with Cl-vIl centering the anionic [ClO4](-) tetrahedra, and Cl-1 centering the edge-sharing [ClBa4](7+) anion-centered tetrahedra is reported. SHG measurements confirm SHG activity of 1 as 5-6 SiO2 units. The polarity in the structure of 1 is resulted from the orientation of the perchlorate anions. (C) 2017 Elsevier B.V. All rights reserved.

引用

页码：174 / 177

页数：4

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