Copper-Catalyzed Single C-H Amination of 8-Aminoquinoline-Directed Ferrocenes

被引：18

作者：

Kanemoto, Kazuya ^{[1
]}

Horikawa, Nao ^{[1
]}

Hoshino, Shun ^{[1
]}

Tokoro, Yuichiro ^{[1
,2
]}

Fukuzawa, Shin-Ichi ^{[1
]}

机构：

[1] Chuo Univ, Inst Sci & Engn, Dept Appl Chem, Tokyo 1128551, Japan

[2] Natl Def Acad Japan, Sch Appl Sci, Dept Appl Chem, 1-10-20 Hashirimizu, Yokosuka, Kanagawa 2398686, Japan

来源：

ORGANIC LETTERS | 2021年 / 23卷 / 13期

关键词：

PLANAR CHIRAL FERROCENES; BOND FORMATION; AMIDATION; COMPLEXES; RECOGNITION; ARYLATION; LIGANDS; OXIDE; UNITS;

D O I：

10.1021/acs.orglett.1c01294

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

An unprecedented copper-catalyzed C-H mono-amination of ferrocenes directed by an 8-aminoquinoline amide directing group is described. This reaction proceeds in the presence of a catalytic amount of copper catalyst with both cyclic and acyclic amines to afford the various aminoferrocenes. The C-H amination of ortho-substituted ferroceneamides was also achieved, enabling rapid access to multisubstituted ferrocenes that are useful for developing new functional molecules.

引用

页码：4966 / 4970

页数：5

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