Depositional age, provenance, and tectonic setting of the Neoproterozoic Sibao Group, southeastern Yangtze Block, South China

The Sibao Group on the southeastern margin of the Yangtze Block of South China is composed mainly of flysch turbidites up to ca. 4000 m thick. Sandstones from the Sibao Group have intermediate to high SiO2 (58.6-80.0 wt%, average 68.2 wt%) and Al2O3 wt% (7.4-20.6 wt%, average 15 wt%), typical of immature lithic varieties. Both sandstones and mudstones contain high K2O (1.41-6.28 wt%) but extremely low Na2O (0.03-1.49 wt%). Positive correlations between Al2O3 and Fe2O3(T), TiO2, MgO and K2O, significant depletion of Ca, Na and Sr relative to upper continental crust and high PIA and pre-metasomatism CIA values suggest that intensive chemical weathering of the source area. Variable Cr/Th (3.9-37.0) and Co/Th (0.2-3.2) ratios indicate a source with predominant felsic and minor mafic components. Discrimination diagrams involving Ti, Al, Fe, La, Th, Sc, Hf and Co reveal the source with multiple lithologies consisting mainly of TM-like, granitic, andesitic and felsic volcanic rocks. Predominant detrital zircons have Neoproterozoic ages from 822 to 980 Ma, whereas the remaining zircons define two age groups at 1.35-2.22 Ga and 2.32-2.86 Ga. Twenty-six of the youngest grains have a weighted mean age of 835.3 +/- 3.6 Ma, tentatively interpreted as the maximum depositional age of the Sibao Group. Neoproterozoic zircon grains have variable Hf-177/Hf-176 ratios (0.281194 to 0.282564) and epsilon(Hf(t)) values (-35.9 to 9.8), indicative of the involvement of juvenile and ancient recycled components. The 1.4 and 1.8 Ga zircon grains have variable Hf-177/Hf-176 ratios (0.280947-0.281874), probably reflecting the growth of the supercontinent Columbia and suggesting that the Yangtze Block was separated from Columbia as an independent terrane at around 1.4 Ga. The complicated provenance involving felsic to intermediate rocks and Neoproterozoic juvenile to Neoarchean mature materials suggests that the Neoproterozoic Sibao Group was deposited in a back-arc foreland basin related to the northward (present coordinate) subduction of an oceanic lithosphere beneath the southeastern Yangtze Block. (C) 2011 Elsevier B.V. All rights reserved.