Stereochemical control of cis- and trans-TiCl2 groups in six-coordinate complexes [(L)TiCl2] (L2- = N2O2-donor Schiff base) and reactions with trimethylaluminium to form cationic aluminium species

被引：80

作者：

Corden, JP ^{[1
]}

Errington, W ^{[1
]}

Moore, P ^{[1
]}

Wallbridge, MGH ^{[1
]}

机构：

[1] Univ Warwick, Dept Chem, Coventry CV4 7AL, W Midlands, England

来源：

CHEMICAL COMMUNICATIONS | 1999年 / 04期

关键词：

D O I：

10.1039/a808372j

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The first example of a cis-configuration of the TiCl2 group in a six-coordinate titanium complex [(L)TiCl2], involving a tetradentate N2O2-donor Schiff base ligand (L2-), is reported, and reactions of such complexes with trimethyl aluminium have been shown to generate cationic aluminium species.

引用

页码：323 / 324

页数：2

共 10 条

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[7] Photoinduced isomerisation of cis-[M(L-S,O)2] (M = PtII and PdII) complexes of N,N-diethyl-N'-3,4,5-trimethoxybenzoylthiourea:: key to preparation of the trans isomer
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[9] Article Ten-Coordinate Lanthanide [Ln(HL)(L)] Complexes (Ln = Dy, Ho, Er, Tb) with Pentadentate N3O2-Type Schiff-Base Ligands: Synthesis, Structure and Magnetism
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[10] Zinc(II) complexes derived from the di-Schiff-base ligand N,N′-bis[1(pyridin-2-yl)ethylidene]ethane-1,2-diamine (LA) and its hydrolytic-cleavage product N-[1-pyridin-2-yl)ethylidene]ethane-1,2-diamine (L):: preparation, characterization and crystal structure of the 5-coordinate species [ZnLCl2]
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