Photoinduced isomerisation of cis-[M(L-S,O)2] (M = PtII and PdII) complexes of N,N-diethyl-N'-3,4,5-trimethoxybenzoylthiourea:: key to preparation of the trans isomer

被引：30

作者：

Hanekom, D ^{[1
]}

McKenzie, JM ^{[1
]}

Derix, NM ^{[1
]}

Koch, KR ^{[1
]}

机构：

[1] Univ Stellenbosch, Dept Chem, ZA-7602 Stellenbosch, South Africa

来源：

CHEMICAL COMMUNICATIONS | 2005年 / 06期

关键词：

D O I：

10.1039/b415306e

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

In acetonitrile solutions at room temperature, cis-[M(L-S,O)(2)] Pt-II and Pd-II complexes of N,N-diethyl-N'-3,4,5-trimethoxybenzoylthiourea undergo reversible photoinduced isomerisation to the corresponding trans isomer upon irradiation with visible light in the 320 - 570 nm range, the rate and extent of isomerisation being significantly higher for the cis-[Pd(L-S, O)(2)] complex compared to the PtII analogue; in the dark trans-[M(L- S, O)(2)] cleanly reverts back to the cis complex at a rate dependent on the solution temperature, indicating a thermally controlled reverse process.

引用

页码：767 / 769

页数：3

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