The synthesis and structural characterization of a novel Bi-Mo double cubane cluster coupled by two bridging oxygen atoms {[Mo3(BiI3)OS3(μ-OAc)2(py)3]2(μ-O)2}•2(H2O)

被引：7

作者：

Lu, SF ^{[1
]}

Huang, JQ ^{[1
]}

Wu, QJ ^{[1
]}

Huang, XY ^{[1
]}

Wu, DX ^{[1
]}

Zheng, Y ^{[1
]}

Yu, RM ^{[1
]}

机构：

[1] Chinese Acad Sci, Fujian Inst Res Struct Matter, State Key Lab Struct Chem, Fujian 350002, Peoples R China

来源：

POLYHEDRON | 1998年 / 18卷 / 1-2期

基金：

中国国家自然科学基金;

关键词：

Mo-Bi-S(O) double cubane cluster; synthesis; crystal structure; spectrum;

D O I：

10.1016/S0277-5387(98)00296-4

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

With [Mo-3(mu(3)-O) (mu-S)(3)(mu-OAc)(2)(dtp)(2)(py)](dtp = S2P(OC2H5)(2))(-); OAc = OOCCH3-; py = C5H5N) as the starting material, the reaction together with BiI3 in presence of (H2O) results in a novel Bi-Mo double-cubane cluster coupled by two bridging oxygen atoms {[Mo-3(BiI3)(mu(3)-O) (mu(3)-S)(3) (mu-OAc)(2)(py)(3)](2)(mu-O)(2)}. 2(H2O) 2. The cluster 2 has been characterized by IR, Raman, UV-Vis, NMR and single-crystal X-ray study. A comparison is made between these results and those of the previously reported single cubane Bi-Mo cluster [Mo-3(BiI3) (mu(3)-S)(4)(mu-OAc) (dtp)(3)(py)] 1. (C) 1998 Elsevier Science Ltd. All rights reserved.

引用

页码：281 / 287

页数：7

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