Rhodium/chiral diene-catalyzed asymmetric methylation of N-sulfonylarylimines with trimethylboroxine

被引：11
|
作者：
Nishimura, Takahiro [1 ]
Ashouri, Akram [1 ]
Ebe, Yusuke [1 ]
Maeda, Yuko [1 ]
Hayashi, Tamio [1 ]
机构：
[1] Kyoto Univ, Grad Sch Sci, Dept Chem, Sakyo Ku, Kyoto 6068502, Japan
来源：
TETRAHEDRON-ASYMMETRY | 2012年 / 23卷 / 09期
关键词：
ENANTIOSELECTIVE ADDITION; DIORGANOZINC REAGENTS; DIALKYLZINC REAGENTS; ARYLBORONIC ACIDS; STEERING LIGANDS; ORGANOMETALLIC REAGENTS; ORGANOBORON REAGENTS; CHIRAL OLEFINS; 1,4-ADDITION; IMINES;
D O I：
10.1016/j.tetasy.2012.04.021
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
A hydroxorhodium complex coordinated with a chiral diene ligand catalyzed the asymmetric addition of trimethylboroxine to N-sulfonylarylimines to give high yields of chiral 1-aryl-1-ethylamines with high enantioselectivity. (C) 2012 Elsevier Ltd. All rights reserved.
引用
收藏
页码：655 / 658
页数：4
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