1-{1-[2,8-Bis(trifluoromethyl)-4-quinolyl]-5-methyl-1H-1,2,3-triazol-4-yl}ethanone

被引:2
|
作者
Devarajegowda, H. C. [1 ]
Jeyaseelan, S. [1 ]
Sumangala, V. [2 ]
Bojapoojary [3 ]
Nayak, Suresh P. [3 ]
机构
[1] Univ Mysore, Dept Phys, Yuvarajas Coll, Mysore 570005, Karnataka, India
[2] Sequent Sci India Ltd, Baikampadi Mangalore, Karnataka, India
[3] Mangalore Univ, Dept Chem, Mangalagangothri 574199, Karnataka, India
关键词
GROWTH-INHIBITION; TRIAZOLES; AGENTS;
D O I
10.1107/S1600536810034926
中图分类号
O7 [晶体学];
学科分类号
0702 ; 070205 ; 0703 ; 080501 ;
摘要
There are two independent molecules in the asymmetric unit of the title compound, C(16)H(10)F(6)N(4)O. The triazole ring is not coplanar with the quinoline ring system; the dihedral angle between the two planes being 74.47 (12) and 63.97 (13)degrees in the two molecules. The crystal structure is characterized by intermolecular C-H center dot center dot center dot F, C-H center dot center dot center dot N and C-H center dot center dot center dot O hydrogen bonding. Weak intramolecular C-H center dot center dot center dot F interactions are observed. Disorder is observed in two F atoms of one of the trifluoromethyl groups of one independent molecule [ occupancy ratios 0.77 (3): 0.23 (3) and 0.77 (4): 0.23 (4)] and in all three F atoms of one of the trifluoromethyl groups of the second independent molecule [ occupancy ratios 0.520 (14): 0.480 (14), 0.615 (17): 0.385 (17) and 0.783 (11): 0.217 (11)]. The O atom is also disordered over two positions with occupancies of 0.60 (13) and 0.40 (13) in the first molecule.
引用
收藏
页码:O2512 / U37
页数:15
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