Synthesis Metal-Organic Framework (MOFs) Cr-PTC-HIna Modulated Isonicotinic Acid for Methylene Blue Photocatalytic Degradation

被引：4

作者：

Adawiah, Adawiah ^{[1
]}

Oktavia, Wulandari ^{[2
]}

Saridewi, Nanda ^{[3
]}

Azhar, Farhan Maulana ^{[2
]}

Fitria, Risma Nur ^{[2
]}

Gunawan, Muhammad Shofyan ^{[2
]}

Komala, Sri ^{[2
]}

Zulys, Agustino ^{[4
]}

机构：

[1] UIN Syarif Hidayatullah Jakarta, Fac Sci & Technol, Integrated Lab Ctr, Jl Ir H Juanda 95 Ciputat, Tangerang Selatan 15412, Indonesia

[2] UIN Syarif Hidayatullah Jakarta, Fac Sci & Technol, Dept Chem, Jl Ir H Juanda 95 Ciputat, Tangerang Selatan 15412, Indonesia

[3] UIN Syarif Hidayatullah Jakarta, Fac Tarbiya & Teaching Sci, Dept Chem Educ, Jl Ir H Juanda 95 Ciputat, Tangerang Selatan 15412, Indonesia

[4] Univ Indonesia, Fac Math & Nat Sci, Dept Chem, Jl Lingkar Kampus Raya, Depok 16424, Jawa Barat, Indonesia

来源：

BULLETIN OF CHEMICAL REACTION ENGINEERING AND CATALYSIS | 2022年 / 17卷 / 02期

关键词：

Isonicotinic acid; methylene blue; Cr-PTC-HIna; photocatalyst; solvothermal; ADSORPTION; TOPOLOGY; REMOVAL;

D O I：

10.9767/bcrec.17.2.13930.383-393

中图分类号：

TQ [化学工业];

学科分类号：

0817 ;

摘要：

A novel responsive visible light Cr-based MOF, Cr-PTC-HIna, was synthesized using the solvothermal method. Cr-PTC-HIna peaks were observed at 2 theta = 9.04 degrees, 12.71 degrees, 14.88 degrees, 25,48 degrees, 27.72 degrees, 28.97 degrees, and 43.60 degrees with a crystal size of 21 nm. Band gap energy achieved from the Cr-PTC HIna was 2.05 eV. Scanning Electron Microscope (SEM) analysis obtained a 3D structural morphology of MOFs Cr-PTC-HIna with a cylindrical tube shape and a particle size of 251.45 nm. Cr-PTC-HIna gave the optimum methylene blue degradation at pH of 7 under 250 watts mercury lamp irradiation for 180 minutes with degradation capacity of 95.40 mg/g. Electron holes and hydroxyl radicals were found as the dominant species contributing to methylene blue degradation. Copyright (c) 2022 by Authors, Published by BCREC Group. This is an open access article under the CC BY-SA License (https://creativecommons. org/licenses/by-sa/4.0).

引用

页码：383 / 393

页数：11

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