Copper-Catalyzed Sonogashira Reaction in Water

被引：31

作者：

Liu, Yujia ^{[1
]}

Blanchard, Vincent ^{[1
]}

Danoun, Gregory ^{[1
]}

Zhang, Zhaoyang ^{[2
]}

Tlili, Anis ^{[1
]}

Zhang, Wenlong ^{[2
]}

Monnier, Florian ^{[1
]}

Van der Lee, Arie ^{[3
]}

Mao, Jincheng ^{[2
]}

Taillefer, Marc ^{[1
]}

机构：

[1] Inst Charles Gerhardt, CNRS, Ecole Natl Super Chim Montpellier, UMR 5253, 8 Rue Ecole Normale, F-34296 Montpellier 05, France

[2] Southwest Petr Univ, State Key Lab Oil & Gas Reservoir Geol & Exploita, Chengdu 610500, Sichuan, Peoples R China

[3] Univ Montpellier, CNRS, Inst Europeen Membranes, ENSCM,UMR 5635, F-34095 Montpellier 5, France

来源：

CHEMISTRYSELECT | 2017年 / 2卷 / 35期

关键词：

copper-catalyzed; mechanism; Sonogashira; turn-over; water; PALLADIUM-FREE CONDITIONS; ARYL IODIDES; COUPLING REACTIONS; TERMINAL ALKYNES; CONJUGATED ENYNES; BOND FORMATION; VINYL IODIDES; ARYLATION; EFFICIENT; LIGANDS;

D O I：

10.1002/slct.201702854

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Copper-catalyzed Sonogashira reaction has been realized under biphasic conditions (water / organic substrates) allowing decreasing the copper loading up to 0.02-0.2 mol %. A potential intermediate species of the reaction, corresponding to a copper cluster linked with acetylide moiety, has been identified.

引用

页码：11599 / 11602

页数：4

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