Formation and Structural Characterization of Metal Complexes derived from Thiosalicylic Acid

被引：5

作者：

Bhowon, Minu G. ^{[1
]}

Jhaumeer-Laulloo, Sabina ^{[1
]}

Moosun, Salma ^{[1
]}

Humphreys, Lisa ^{[3
]}

Coles, Simon ^{[2
]}

Fowdram, Roshni ^{[1
]}

Mungra, Evena ^{[1
]}

机构：

[1] Univ Mauritius, Dept Chem, Fac Sci, Reduit 80837, Mauritius

[2] Univ Southampton, Fac Nat & Environm Sci, Chem, Southampton SO17 1BJ, Hants, England

[3] Cranfield Univ, Ctr Def Chem, Def Acad United Kingdom, Shrivenham SN6 8LA, England

来源：

ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE | 2017年 / 643卷 / 18期

关键词：

Thiosalicylic acid; Dithiodibenzoic acid; Thiodibenzoic acid; X-ray diffraction; CRYSTAL-STRUCTURES; HYDROTHERMAL SYNTHESIS; LIGANDS; ZN(II);

D O I：

10.1002/zaac.201700244

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The formation and structural aspects of some metal complexes of thiosalicylic acid (TSA) were studied. The -bridging tetra-coordinated Ru complex, [Ru(C6H4(CO2)(mu-S)(H2O)](2) (1) was formed by hydrothermal reaction of TSA with RuCl3. The complexes [M(dtdb)(phen)(H2O)](n) (2-4) (M = Zn-II, Co-II, Ni-II, dtdb = 2,2-dithiodibenzoate anion, phen = 1,10-phenanthroline) were obtained by the slow diffusion technique and the in situ S-S bond formation was confirmed by elemental, spectral and X-ray analysis. Reaction of TSA with CuCl2 and 2,2'-bipyridine (bipy) under the slow diffusion technique yielded the dimer [Cu(tdb)(bipy)] (5) (tdb = thiodibenzoic acid), where the in situ generation of 2,2'-thiodibenzoic acid was observed.

引用

页码：1167 / 1172

页数：6

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