Synthesis and Characterization of New Pyrospirophosphoranes Containing a P-O-P Bond by the Atherton-Todd Reaction

被引：7

作者：

You, Xiaohui ^{[1
]}

Qi, Lin ^{[1
]}

Zheng, Jia ^{[1
]}

Dai, Wang ^{[1
]}

Guo, Yanchun ^{[1
]}

Zhao, Yufen ^{[1
,2
]}

Cao, Shuxia ^{[1
]}

机构：

[1] Zhengzhou Univ, Coll Chem & Mol Engn, Key Lab Chem Biol & Organ Chem Henan Prov, Zhengzhou 450052, Peoples R China

[2] Xiamen Univ, Dept Chem, Coll Chem & Chem Engn, Key Lab Chem Biol Fujian Prov, Xiamen 361005, Peoples R China

来源：

HETEROATOM CHEMISTRY | 2015年 / 26卷 / 02期

基金：

中国国家自然科学基金;

关键词：

H-PHOSPHONATES; SPIROPHOSPHORANES; STEREOCHEMISTRY; HYDROLYSIS;

D O I：

10.1002/hc.21243

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The classical Atherton-Todd reaction has been successfully applied to the synthesis of pentacoordinate pyrospirophosphoranes containing a P-O-P bond under mild conditions. The absolute configurations of the products were confirmed by X-ray diffraction analysis and spectroscopic identification. And P-31 NMR chemical shifts of the products were correlated with stereochemistry. A possible mechanism for explaining the stereochemistry of the reaction was proposed, and it could well explain the results of the reactions of different pentacoordinate hydrospirophosphoranes.

引用

页码：168 / 174

页数：7

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