2,2′-Bipyridinium bis(perchlorate)

被引：14
|
作者：
Ma, GB
Ilyukhin, A
Glaser, J [1 ]
机构：
[1] Royal Inst Technol, Dept Chem, S-10044 Stockholm, Sweden
[2] Russian Acad Sci, NS Kurnakov Gen & Inorgan Chem Inst, Moscow 117907, Russia
来源：
ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS | 2000年 / 56卷 / 12期
关键词：
D O I：
10.1107/S0108270100012452
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
The title compound, [H(2)bipy](ClO4)(2) or C10H10N22+. 2ClO(4)(-), was obtained at the interface between an organic (2,2'-bipyridine in methanol) and an aqueous phase (perchloric acid in water). The compound crystallizes in space group P(1) over bar and comprises discrete diprotonated trans-bipyridinium cations, [H(2)bipy](2+), and ClO4- anions. The cations and anions are connected through N-H . . .O and C-H . . .O hydrogen bonds [distances N . . .O 2.817 (4) and 2.852 (4) Angstrom, and C . . .O 3.225 (6)-3.412 (5)Angstrom]. The C-C bond distance between the two rings is 1.452 (5) Angstrom. The bipyridinium cation has a trans conformation and the N-C-C-N torsion angle is 152.0 (3)degrees.
引用
收藏
页码：1473 / 1475
页数：3
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