Iron-catalyzed sulfonyl radical formations from sulfonylhydrazides and oxidative addition to alkenes

被引：165
|
作者：
Taniguchi, Tsuyoshi [1 ]
Idota, Atsushi [1 ]
Ishibashi, Hiroyuki [1 ]
机构：
[1] Kanazawa Univ, Sch Pharmaceut Sci, Inst Med Pharmaceut & Hlth Sci, Kanazawa, Ishikawa 9201192, Japan
来源：
ORGANIC & BIOMOLECULAR CHEMISTRY | 2011年 / 9卷 / 09期
关键词：
D O I：
10.1039/c0ob01119c
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
Generation of sulfonyl radicals from sulfonylhydrazides has been achieved in the presence of a non-toxic iron catalyst and oxygen. The intermolecular addition of resultant sulfonyl radicals to alkenes affords beta-hydroxysulfone compounds.
引用
收藏
页码：3151 / 3153
页数：3
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