Polarographic behavior of phosphorus tribromide

被引：0

作者：

Kisil', LM ^{[1
]}

Osadchenko, IM ^{[1
]}

Tomilov, AP ^{[1
]}

机构：

[1] State Res Inst Organ Chem & Technol, Moscow, Russia

来源：

RUSSIAN JOURNAL OF GENERAL CHEMISTRY | 2003年 / 73卷 / 05期

关键词：

Phosphorus; Mercury; Acetonitrile; Analytical Purpose; Cathodic Process;

D O I：

10.1023/A:1026166315667

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Phosphorus tribromide gives a one-electron reduction wave at E-1/2 -0.6 V on a mercury drop cathode in acetonitrile in the concentration range 0.05-0.5 mM, applicable for analytical purposes. It is proposed that the cathodic process gives rise to an unstable species particle PBr which is adsorbed on the mercury surface.

引用

页码：695 / 696

页数：2

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