Large diameter non-covalent nanotubes based on the self-assembly of para-carboxylatocalix[4]arene

被引:37
|
作者
Dalgarno, Scott J.
Warren, John E.
Antesberger, Jochen
Glass, Timothy E.
Atwood, Jerry L.
机构
[1] Univ Missouri, Dept Chem, Columbia, MO 65211 USA
[2] SERC, Daresbury Lab, Stn 9 8, Warrington WA4 4AD, Cheshire, England
关键词
D O I
10.1039/b712800b
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Non-covalent nanotubular assemblies with large core diameters are rare. Here we show that simple crystallisation of paracarboxylatocalix[4]arene from pyridine results in the formation of one such assembly, facilitated by back-to-back packing of calixarenes and the well known pyridine-carboxylic acid interaction.
引用
收藏
页码:1891 / 1894
页数:4
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