Nitrogen-rich 6-(3,5-dimethylpyrazol-1-yl)-3-(2,4,6-trinitroanilino)-1,2,4,5-tetrazin: synthesis, crystal structure and thermal property

被引：3
|
作者：
Pan Wan-Long
Huang Kun-Lin
Tang Wang
Xu Yan-Qing
Hu Chang-Wen [1 ]
机构：
[1] Beijing Inst Technol, State Key Lab Explos Sci & Technol, Dept Chem, Beijing 100081, Peoples R China
[2] Beijing Inst Technol, Inst Chem Phys, Beijing 100081, Peoples R China
[3] Chongqing Normal Univ, Coll Chem, Chongqing 400047, Peoples R China
来源：
CHINESE JOURNAL OF CHEMISTRY | 2007年 / 25卷 / 10期
关键词：
tetrazine; trinitroaniline; synthesis; crystal structure; helix;
D O I：
10.1002/cjoc.200790268
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
6-(3,5-Dimethylpyrazol-1-yl)-3-(2,4,6-trinitroanilino)-1,2,4,5-tetrazin (1) has been synthesized and characterized by H-1 NMR, MS, elemental analysis, infrared spectra and thermal analyses. The crystal structure was determined by X-ray diffraction method. 1 is crystallized in P21/c space group of monoclinic crystal system, and exhibits good physical properties, such as high densities (> 1.55 g center dot cm(-3)) and good thermal stabilities (T-d>220 degrees C). The intrermolecular hydrogen bonds construct the P- and M-helices from organic molecules and may contribute to the high melting points.
引用
收藏
页码：1451 / 1454
页数：4
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