Bond dissociation enthalpies of U(IV) complexes. An integrated view

被引：15
|
作者：
Leal, JP [1 ]
Marques, N
Takats, J
机构：
[1] ITN, Dept Quim, P-2686953 Sacavem, Portugal
[2] Univ Alberta, Dept Chem, Edmonton, AB T6G 2G2, Canada
来源：
JOURNAL OF ORGANOMETALLIC CHEMISTRY | 2001年 / 632卷 / 1-2期
关键词：
bond dissociation enthalpy; uranium compounds;
D O I：
10.1016/S0022-328X(01)01068-3
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
A brief overview of the bond dissociation enthalpies in U(IV) organometallic compounds published earlier is made. Some new results of the bond dissociation enthalpies on U(IV) compounds (kJ mol(-1)), D(U-1) = 260 +/- 11, D(U-O) = 307 +/- 13, D(U-Cl) = 369 +/- 14 and D(U-Cl) = 341 +/- 19, are presented and used to discuss the literature data critically. (C) 2001 Elsevier Science B.V. All rights reserved.
引用
收藏
页码：209 / 214
页数：6
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