(+)-{1,2-Bis[(2R,5R)-2,5-diethylphospholan-1-yl]ethane-κ2P,P′}(η4-cycloocta-1,5-diene)rhodium(I) tetrafluoridoborate

被引：0

作者：

Schulz, Stefan ^{[1
]}

Fischer, Christian ^{[1
]}

Drexler, Hans-Joachim ^{[1
]}

Heller, Detlef ^{[1
]}

机构：

[1] Univ Rostock, Leibniz Inst Katalyse eV, D-18059 Rostock, Germany

来源：

ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE | 2010年 / 66卷

关键词：

HYDROGENATION; PRECATALYSTS; CATALYSIS; OLEFINS;

D O I：

10.1107/S1600536810039577

中图分类号：

O7 [晶体学];

学科分类号：

0702 ; 070205 ; 0703 ; 080501 ;

摘要：

The title compound, [Rh(C8H12)(C18H36P2)]BF4, exhibits a rhodium(I) complex cation with a bidentate bisphosphine ligand and a bidentate eta(2),eta(2)-coordinated cycloocta-1,5-diene ligand. The ligands form a slightly distorted square-planar coordination environment for the Rh(I) atom. An intramolecular P-Rh-P bite angle of 83.91 (2)degrees is observed. The dihedral angle between the P-Rh-P and the X-Rh-X planes (X is the centroid of a double bond) is 14.0 (1)degrees. The BF4 anion is disordered over two positions in a 0.515 (7):0.485 (7) ratio.

引用

页码：M1370 / U325

页数：11

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