First direct deprotonation-electrophile trapping of simple epoxides:: Synthesis of α,β-epoxysilanes from terminal epoxides

被引：43

作者：

Hodgson, DM ^{[1
]}

Norsikian, SLM ^{[1
]}

机构：

[1] Univ Oxford, Dyson Perrins Lab, Dept Chem, Oxford OX1 3QY, England

来源：

ORGANIC LETTERS | 2001年 / 3卷 / 03期

关键词：

D O I：

10.1021/ol006948f

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

[GRAPHICS] The presence of a suitable diamine ligand is the key to achieving ring lithiation-substitution of epoxides without the need for activating substituents on the epoxide and constitutes a new synthetic entry to trans-alpha,beta -epoxysilanes.

引用

页码：461 / 463

页数：3

共 40 条

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