Preparative routes to organozinc reagents used for organic synthesis

被引：15

作者：

Nakamura, M ^{[1
]}

Nakamura, E ^{[1
]}

机构：

[1] Univ Tokyo, Grad Sch Sci, Dept Chem, Bunkyo Ku, Tokyo 1130033, Japan

来源：

JOURNAL OF SYNTHETIC ORGANIC CHEMISTRY JAPAN | 1998年 / 56卷 / 08期

关键词：

organozinc reagent; preparative methods; C-C bond forming reactions; polyfunctionalized organometallics; selective organometallic reagent; oxidative zincation; transmetalation; halogen-zinc exchange;

D O I：

10.5059/yukigoseikyokaishi.56.632

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Organozinc reagents have become extremely important synthetic tools in recent years, and the useful and practical preparative routes to such reagents have been reviewed. The methods have been classified into four broad categories, (1) oxidative zincation method, (2) transmetalation method, (3) halogen-zinc exchange, and (4) others. Each categories are subdivided according to the type of organic groups on the zinc atom (alkyl, alkenyl, etc.).

引用

页码：632 / 644

页数：13

共 50 条

[21] ULTRASOUND IN ORGANIC-SYNTHESIS .6. AN EASY PREPARATION OF ORGANOZINC REAGENTS AND THEIR CONJUGATE ADDITION TO ALPHA-ENONES
PETRIER, C
LUCHE, JL
DUPUY, C
TETRAHEDRON LETTERS, 1984, 25 (32) : 3463 - 3466
[22] INTRAMOLECULAR CARBOMETALATION OF SECONDARY ORGANOZINC REAGENTS
MEYER, C
MAREK, I
COURTEMANCHE, G
NORMANT, JF
TETRAHEDRON LETTERS, 1993, 34 (38) : 6053 - 6056
[23] Chemoselective oxidation of organozinc reagents with oxygen
Klement, I
Lutjens, H
Knochel, P
TETRAHEDRON, 1997, 53 (27) : 9135 - 9144
[24] ENANTIOSELECTIVE ADDITION OF ORGANOZINC REAGENTS TO ALDEHYDES
SOAI, K
NIWA, S
CHEMICAL REVIEWS, 1992, 92 (05) : 833 - 856
[25] Reactions of organozinc reagents with potassium bromodifluoroacetate
Levin, Vitalij V.
Zemtsov, Artem A.
Struchkova, Marina I.
Dilman, Alexander D.
JOURNAL OF FLUORINE CHEMISTRY, 2015, 171 : 97 - 101
[26] Making organozinc reagents more useful
不详
CHEMICAL & ENGINEERING NEWS, 1997, 75 (29) : 28 - 28
[27] USE OF ACTIVATION METHODS FOR ORGANOZINC REAGENTS
ERDIK, E
TETRAHEDRON, 1987, 43 (10) : 2203 - 2212
[28] Advances in tandem reactions with organozinc reagents
Kim, Ju Hyun
Ko, Young Ok
Bouffard, Jean
Lee, Sang-gi
CHEMICAL SOCIETY REVIEWS, 2015, 44 (08) : 2489 - 2507
[29] THE CHEMISTRY OF POLYFUNCTIONAL ORGANOZINC AND COPPER REAGENTS
KNOCHEL, P
ROZEMA, MJ
TUCKER, CE
RETHERFORD, C
FURLONG, M
ACHYUTHARAO, S
PURE AND APPLIED CHEMISTRY, 1992, 64 (03) : 361 - 369
[30] Chemoselective oxidation of organozinc reagents with oxygen
Tetrahedron, 27 (9135):

← 1 2 3 4 5 →