Feasibility of hydrogen production from coal electrolysis at intermediate temperatures

被引:45
|
作者
Jin, Xin [1 ]
Botte, Gerardine G. [1 ]
机构
[1] Ohio Univ, Dept Chem Engn, Athens, OH 45701 USA
关键词
coal electrolysis; hydrogen production; coal gasification; coal conversion; coal utilization; coal electrolytic cell;
D O I
10.1016/j.jpowsour.2007.06.209
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
Hydrogen production via coal electrolysis was evaluated at intermediate temperatures (40-108 degrees C). A coal electrolytic cell (CEC) was designed and constructed to carry out galvanostatic experiments with concentrated electrolyte (4M H2SO4)- Operating temperatures above 100 degrees C were found to significantly improve the kinetics of electro-oxidation of coal, coal conversion, and CO2/coal Faradaic efficiency. CO2/coal Faradaic efficiencies and coal conversions of up to 57.29 and 3.21%, respectively, were observed at 108 degrees C. (C) 2007 Elsevier B.V. All rights reserved.
引用
收藏
页码:826 / 834
页数:9
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