Single-molecule magnet behaviour in a Dy(III) pentagonal bipyramidal complex with a quasi-linear Cl-Dy-Cl sequence

被引：20

作者：

Long, Jerome ^{[1
]}

Selikhov, Alexander N. ^{[2
]}

Mamontova, Ekaterina ^{[1
]}

Lyssenko, Konstantin A. ^{[3
]}

Guari, Yannick ^{[1
]}

Larionova, Joulia ^{[1
]}

Trifonov, Alexander A. ^{[2
,3
]}

机构：

[1] Univ Montpellier, ENSCM, CNRS, Inst Charles Gerhardt,Equipe Ingn Mol & Nanoobjet, Pl Eugene Bataillon, F-34095 Montpellier 5, France

[2] Russian Acad Sci, Inst Organometall Chem, 49 Tropinina Str,GSP 445, Nizhnii Novgorod 630950, Russia

[3] Russian Acad Sci, Inst Organoelement Cpds, 28 Vavilova Str, Moscow 119334, Russia

来源：

DALTON TRANSACTIONS | 2019年 / 48卷 / 01期

基金：

俄罗斯科学基金会;

关键词：

LUMINESCENCE; RELAXATION; ANISOTROPY; DESIGN;

D O I：

10.1039/c8dt04098b

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

We report the synthesis and magnetic investigation of a dysprosium pentagonal bipyramidal complex [Dy(THF)Cl-5(2)][BPh4] (1) exhibiting a linear Cl-Dy-Cl sequence suitable for providing a coordination environment allowing a zero-field slow relaxation of the magnetization. Besides, the complex also shows dual luminescence originating from [BPh4](-) and Dy3+.

引用

页码：35 / 39

页数：5

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