The First {Dy4} Single-Molecule Magnet with a Toroidal Magnetic Moment in the Ground State

被引：186
|
作者：
Guo, Peng-Hu [3 ]
Liu, Jun-Liang [3 ]
Zhang, Ze-Min [3 ]
Ungur, Liviu [1 ,2 ]
Chibotaru, Liviu F. [1 ,2 ]
Leng, Ji-Dong [3 ]
Guo, Fu-Sheng [3 ]
Tong, Ming-Liang [3 ]
机构：
[1] Katholieke Univ Leuven, Div Quantum & Phys Chem, B-3001 Louvain, Belgium
[2] Katholieke Univ Leuven, Inst Nanoscale Phys & Chem INPAC, B-3001 Louvain, Belgium
[3] Sun Yat Sen Univ, State Key Lab Optoelect Mat & Technol, MOE Key Lab Bioinorgan & Synthet Chem, Sch Chem & Chem Engn, Guangzhou 510275, Guangdong, Peoples R China
来源：
INORGANIC CHEMISTRY | 2012年 / 51卷 / 03期
关键词：
DYSPROSIUM TRIANGLES; ANISOTROPIC BARRIER; SPIN STATES; RELAXATION; BEHAVIOR;
D O I：
10.1021/ic202650f
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
A toroidal magnetic moment in the absence of a conventional total magnetic moment was first observed in a novel tetranuclear dysprosium cluster with nonmagnetic ground state. The toroidal state is quite robust with respect to variations of the exchange parameters.
引用
收藏
页码：1233 / 1235
页数：3
相关论文
共 50 条
  • [21] Dy4 and Dy5 complexes based on tautomeric hydrazone Schiff-base ligand regulated by temperature showing single-molecule magnet behaviour
    Zhong, Xiang
    Hu, Zhao-Bo
    Luo, Tong-Kai
    Chen, Xiao-Feng
    Zhang, Qing-Yun
    Peng, Yan
    Liu, Sui-Jun
    Wen, He-Rui
    JOURNAL OF MOLECULAR STRUCTURE, 2024, 1311
  • [22] Hexanuclear [Cp*Dy]6 single-molecule magnet
    Wu, Jianfeng
    Demeshko, Serhiy
    Dechert, Sebastian
    Meyer, Franc
    CHEMICAL COMMUNICATIONS, 2020, 56 (27) : 3887 - 3890
  • [23] Probing the magnetic relaxation and magnetic moment arrangement in a series of Dy4 squares
    Wu, Jianfeng
    Lin, Shuang-Yan
    Shen, Si
    Li, Xiao-Lei
    Zhao, Lang
    Zhang, Li
    Tang, Jinkui
    DALTON TRANSACTIONS, 2017, 46 (05) : 1577 - 1584
  • [24] Dramatic impact of auxiliary ligands on the two-step magnetic relaxation process in Dy4(III) single-molecule magnets
    Zhang, Kun
    Li, Gao-Peng
    Zhang, Cheng
    Wang, Yao-Yu
    DALTON TRANSACTIONS, 2019, 48 (17) : 5793 - 5799
  • [25] A {Cr2Dy4} compressed octahedron: the first sulfate-based single-molecule magnet
    Xiang, Hua
    Lu, Wen-Guan
    Zhang, Wei-Xiong
    Jiang, Long
    DALTON TRANSACTIONS, 2013, 42 (04) : 867 - 870
  • [26] An oxide-bridged Dy-ReV-Dy single-molecule magnet
    Pedersen, Kasper S.
    Dreiser, Jan
    Schau-Magnussen, Magnus
    Thuesen, Christian Aa.
    Weihe, Hogni
    Bendix, Jesper
    POLYHEDRON, 2012, 46 (01) : 47 - 52
  • [27] Tuning the Magnetic Interactions in Dy(III)4 Single-Molecule Magnets
    Zhang, Kun
    Montigaud, Vincent
    Cador, Olivier
    Li, Gao-Peng
    Le Guennic, Boris
    Tang, Jin-Kui
    Wang, Yao-Yu
    INORGANIC CHEMISTRY, 2018, 57 (14) : 8550 - 8557
  • [28] Structures and magnetic properties of rhombus-shaped tetranuclear [Ln4] clusters: Dy4 cluster displaying single molecule magnet behavior
    Ji, Jia
    Jiang, Kai-Jun
    Shen, Hai-Yun
    Tian, Yan
    Hou, Yin-Ling
    Gao, Hong-Ling
    Wang, Wen-Min
    Cui, Jian-Zhong
    JOURNAL OF MOLECULAR STRUCTURE, 2021, 1228
  • [29] A novel Dy4 cluster constructed by an 8 hydroxyquinoline Schiff base showing remarkable single molecule magnet behavior
    Wang, Hai-Tang
    Pu, Jin-Rong
    Li, Xin
    Zhang, Yue
    Zhang, Ying
    Li, Li
    Fang, Ming
    POLYHEDRON, 2021, 200 (200)
  • [30] A polyoxometalate-based single-molecule magnet with an S=21/2 ground state
    Fang, Xikui
    Koegerler, Paul
    Speldrich, Manfred
    Schilder, Helmut
    Luban, Marshall
    CHEMICAL COMMUNICATIONS, 2012, 48 (09) : 1218 - 1220
12345