Rhodium(III)-Catalyzed [2+2+2] Cyclotrimerization of Diynes with Maleic Anhydrides as Alkyne Equivalents

被引：9
|
作者：
Matsuda, Takanori [1 ]
Suzuki, Kentaro [1 ]
机构：
[1] Tokyo Univ Sci, Dept Appl Chem, Shinjuku Ku, Tokyo 1628601, Japan
来源：
EUROPEAN JOURNAL OF ORGANIC CHEMISTRY | 2015年 / 2015卷 / 14期
基金：
日本学术振兴会;
关键词：
Synthetic methods; Homogeneous catalysis; Rhodium; Cyclotrimerization; Anhydrides; Alkynes; N BOND FORMATION; DECARBOXYLATIVE CYCLOADDITION; DIELS-ALDER; COMPLEXES; CATALYSTS; PYRIDINES; VERSATILE; BENZENES; ROUTE;
D O I：
10.1002/ejoc.201500252
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
Substituted maleic anhydrides function as synthetic equivalents of alkynes in a rhodium(III)-catalyzed reaction with 1,6-diynes to achieve a formal [2+2+2] cyclotrimerization. This approach is useful for reactions involving alkynes with low boiling points or severe ring strain. Hard-to-access [2+2+2] cycloadducts are available through this new cycloaddition strategy by employing easy-to-handle alkyne equivalents.
引用
收藏
页码：3032 / 3035
页数：4
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