Mild catalytic oxidation of secondary and tertiary amines to nitrones and N-oxides with H2O2 mediated by Pt(II) catalysts

被引：56
|
作者：
Colladon, Marco [1 ]
Scarso, Alessandro [1 ]
Strukul, Giorgio [1 ]
机构：
[1] Univ Ca Foscari Venezia, Dipartimento Chim, I-30123 Venice, Italy
来源：
GREEN CHEMISTRY | 2008年 / 10卷 / 07期
关键词：
D O I：
10.1039/b805404e
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Bridging hydroxo complexes of Pt(II) can be used as catalysts for the oxidation of tertiary and secondary amines under mild conditions using the environmentally benign hydrogen peroxide as the oxidant. The reaction proceeds with medium to excellent yields particularly in the case of the more electron rich tertiary amines.
引用
收藏
页码：793 / 798
页数：6
相关论文
共 50 条
  • [21] Effects of Cu(II) sources on catalytic activity of copper oxides for H2O2 decomposition
    Wang, WL
    Li, DS
    Qin, ZP
    Yue, KF
    Yang, WX
    CHINESE JOURNAL OF CATALYSIS, 2001, 22 (03) : 301 - 303
  • [22] Ts2O mediated deoxygenative C2-dithiocarbamation of quinoline N-oxides with CS2 and amines
    Xie, Long-Yong
    Liu, Chu
    Wang, Si-Yu
    Tian, Zhong-Ying
    Peng, Sha
    RSC ADVANCES, 2024, 14 (20) : 14465 - 14469
  • [23] THE OXIDATION OF FE(II) WITH H2O2 IN SEAWATER
    MILLERO, FJ
    SOTOLONGO, S
    GEOCHIMICA ET COSMOCHIMICA ACTA, 1989, 53 (08) : 1867 - 1873
  • [24] Asymmetric sulfide oxidation with vanadium catalysts and H2O2
    Bolm, C
    Bienewald, F
    ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 1995, 34 (23-24) : 2640 - 2642
  • [25] Asymmetric sulfide oxidation with vanadium catalysts and H2O2
    Fachbereich Chemie der Universität, Hans-Meerwein-Strasse, D-35032 Marburg, Germany
    Angew Chem (Int Ed Engl), 23-24 (2640-2642):
  • [26] Asymmetric sulfide oxidation with vanadium catalysts and H2O2
    Bolm, C.
    Bienewald, F.
    Angewandte Chemie (International Edition in English), 1996, 34 (23-24): : 2640 - 2642
  • [27] Cycloalkane Oxidation Catalyzed by Copper-based Catalysts with H2O2 under Mild Conditions
    Chimlert, Jantira
    Suktanarak, Pattira
    Plainpan, Nukorn
    Paokhan, Mantana
    Tuntulani, Thawatchai
    Leeladee, Pannee
    CHEMISTRYSELECT, 2023, 8 (13):
  • [28] The catalytic oxidation of aqueous phenol by H2O2 using a macrocyclic (N-donor) cobalt(II) complex
    Feng, Fa-mei
    Liu, Fu-an
    Cai, Shu-lan
    Xie, Jia-qing
    PROGRESS IN REACTION KINETICS AND MECHANISM, 2011, 36 (04) : 342 - 351
  • [29] Homogeneous and heterogeneous catalytic oxidation of sulfides by H2O2 over zinc(II) compounds
    Nuzhdin, Alexey L.
    Dybtsev, Danil N.
    Fedin, Vladimir P.
    Bukhtiyarova, Galina A.
    DALTON TRANSACTIONS, 2009, (47) : 10481 - 10485
  • [30] EFFICIENCY OF PT-ALUMINOSILICATE CATALYSTS IN H2O2 DECOMPOSITION
    MARTYNYUK, TG
    POSPELOV.TA
    SHEKHOBA.VI
    KOBOZEV, NI
    ZHURNAL FIZICHESKOI KHIMII, 1973, 47 (05): : 1168 - 1171
12345