Selective C-O bond cleavage of vinyl ethers with Cp*2-Sm(thf)(n) leading to vinylsamarium or enolate complexes

被引:25
|
作者
Takaki, K [1 ]
Maruo, M [1 ]
Kamata, T [1 ]
Makioka, Y [1 ]
Fujiwara, Y [1 ]
机构
[1] KYUSHU UNIV, FAC ENGN, DEPT CHEM SCI & TECHNOL, HIGASHI KU, FUKUOKA 812, JAPAN
来源
JOURNAL OF ORGANIC CHEMISTRY | 1996年 / 61卷 / 23期
关键词
D O I
10.1021/jo961262f
中图分类号
O62 [有机化学];
学科分类号
070303 ; 081704 ;
摘要
[No abstract available]
引用
收藏
页码:8332 / 8334
页数:3
相关论文
共 50 条
  • [41] Metal-Free Synthesis of N-(Pyridine-2-yl)amides from Ketones via Selective Oxidative Cleavage of C(O)-C(Alkyl) Bond in Water
    Liu, Yanpeng
    Sun, Honghao
    Huang, Zhangjian
    Ma, Cong
    Lin, Aijun
    Yao, Hequan
    Xu, Jinyi
    Xu, Shengtao
    JOURNAL OF ORGANIC CHEMISTRY, 2018, 83 (23): : 14307 - 14313
  • [42] Chemistry of unsaturated group 6 metal complexes with bridging hydroxy and methoxycarbyne ligands.: 3.: Formation and cleavage of C-C and C-O bonds in the reactions of the complexes [Mo2CP2(μ-COMe)(μ-COR)(μ-PCy2)]BF4 (R = Me, Et)
    Garcia, M. Esther
    Garcia-Vivo, Daniel
    Ruiz, Miguel A.
    ORGANOMETALLICS, 2008, 27 (04) : 543 - 554
  • [43] Visible light-driven selective cleavage of Cα-Cβ or Cβ-O bond in lignin β-O-4 model into high-value aromatic chemicals over surface modified 2D g-C3N4
    Tan, Hongzi
    Zhang, Pengrui
    Geng, Xuele
    Zhang, Wenhao
    Song, Feng
    Zhao, Rongrong
    Zhang, Keqin
    Cui, Hongyou
    Chen, Xuxing
    Zou, Jian-Ping
    SEPARATION AND PURIFICATION TECHNOLOGY, 2025, 354
  • [44] Nitrogenase Model Complexes [Cp*Fe(μ-SR1)2(μ-η2-R2N=NH)FeCp*] (R1 = Me, Et; R2 = Me, Ph; Cp* = η5-C5Me5): Synthesis, Structure, and Catalytic N-N Bond Cleavage of Hydrazines on Diiron Centers
    Chen, Yanhui
    Zhou, Yuhan
    Chen, Pingping
    Tao, Yinsong
    Li, Yang
    Qu, Jingping
    JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2008, 130 (46) : 15250 - +
  • [45] Nitrogenase model complexes [Cp*Fe(μ-SR1) 2(μ-η2-R2N=NH)FeCp*] (R 1 = Me, Et; R2 = Me, Ph; Cp* = η5- C5Me5): Synthesis, structure, and catalytic N-N bond cleavage of hydrazines on diiron centers
    Chen, Yanhui
    Zhou, Yuhan
    Chen, Pingping
    Tao, Yinsong
    Li, Yang
    Qu, Jingping
    Journal of the American Chemical Society, 2008, 130 (46): : 15250 - 15251
  • [46] N-O bond cleavage and various bonding modes of the nitrato ligand in rhodium complexes:: syntheses and structures of [Cp*Rh((η1-NO3)(μ-Cl]2, {[Cp*RhCl(PPh3)CN-C6H11)]2(NO2)(NO3)}•2H2O, [Cp*Rh(η1-NO3)η1,μ-N3)]2, [Cp*Rh(η2-NO3)(O3SCF3], tans-[Rh(PPh3)2(CN-2,6-Me2C6H3)2](NO3)}•H2O, and {[Cp2*Rh2(η2,μ-NO2-N,O)2(η1,μ-N3)](PF6)}•0.5H2O
    Han, WS
    Lee, SW
    INORGANICA CHIMICA ACTA, 2003, 348 : 15 - 24
  • [47] Reductive Elimination Reactions in Gold(III) Complexes Leading to C(sp3)-X (X = C, N, P, O, Halogen) Bond Formation: Inner-Sphere vs SN2 Pathways
    Portugues, Alejandro
    Martinez-Nortes, Miguel Angel
    Bautista, Delia
    Gonzalez-Herrero, Pablo
    Gil-Rubio, Juan
    INORGANIC CHEMISTRY, 2023, 62 (04) : 1708 - 1718
  • [48] Chemistry of Unsaturated Group 6 Metal Complexes with Bridging Hydroxy and Methoxycarbyne Ligands. 6. C-E Bond Formation and C-O Bond Cleavage Processes in the Reactions of [Mo2(η5-C5H5)2(μ-COMe)(μ-PCy2)(μ-CO)] with Several p-Block Elements (E) and Their Hydride Derivatives
    Esther Garcia, M.
    Garcia-Vivo, Daniel
    Ruiz, Miguel A.
    ORGANOMETALLICS, 2010, 29 (09) : 2157 - 2165
  • [50] Facile CC bond cleavage of polyynediyldiiron complexes, Fp*-(CC)n-Fp* [Fp*=Fe(η5-C5Me5)(CO)2, n = 3, 4], with Fe2(CO)9 leading to bis(μ3-alkylidyne) complexes, Fp*-CC-μ3-C-Fe3(CO)9-μ3-C-(CC)n-2-Fp*
    Akita, M
    Sakurai, A
    Moro-oka, Y
    CHEMICAL COMMUNICATIONS, 1999, (01) : 101 - 102