Phosphinoyl Radical-Initiated α,β-Aminophosphinoylation of Alkenes

被引：46
|
作者：
Li, Jian-An [1 ]
Zhang, Pei-Zhi [1 ]
Liu, Kui [1 ]
Shoberu, Adedamola [1 ]
Zou, Jian-Ping [1 ]
Zhang, Wei [2 ]
机构：
[1] Soochow Univ, Coll Chem & Chem Engn, Key Lab Organ Synth Jiangsu Prov, Suzhou 215123, Peoples R China
[2] Univ Massachusetts, Dept Chem, Boston, MA 02125 USA
来源：
ORGANIC LETTERS | 2017年 / 19卷 / 17期
基金：
中国国家自然科学基金;
关键词：
FLAME-RETARDANT; BETA-HYDROXYPHOSPHONATES; MECHANICAL-PROPERTIES; PHOSPHORUS LIGANDS; ACTIVATED ALKENES; AMP MIMICS; KETOPHOSPHONATES; PHOSPHONATES; ACIDS; FRUCTOSE-1,6-BISPHOSPHATASE;
D O I：
10.1021/acs.orglett.7b02183
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
A new double functionalization reaction of alkenes through AgNO3-mediated phosphinoyl radical addition followed by Cu(II)-catalyzed amination is introduced. This one-pot, three-component reaction is performed under mild conditions to afford alpha,beta-aminophosphinoylation products.
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页码：4704 / 4706
页数：3
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