Phosphinoyl Radical-Initiated α,β-Aminophosphinoylation of Alkenes

被引：46
|
作者：
Li, Jian-An [1 ]
Zhang, Pei-Zhi [1 ]
Liu, Kui [1 ]
Shoberu, Adedamola [1 ]
Zou, Jian-Ping [1 ]
Zhang, Wei [2 ]
机构：
[1] Soochow Univ, Coll Chem & Chem Engn, Key Lab Organ Synth Jiangsu Prov, Suzhou 215123, Peoples R China
[2] Univ Massachusetts, Dept Chem, Boston, MA 02125 USA
来源：
ORGANIC LETTERS | 2017年 / 19卷 / 17期
基金：
中国国家自然科学基金;
关键词：
FLAME-RETARDANT; BETA-HYDROXYPHOSPHONATES; MECHANICAL-PROPERTIES; PHOSPHORUS LIGANDS; ACTIVATED ALKENES; AMP MIMICS; KETOPHOSPHONATES; PHOSPHONATES; ACIDS; FRUCTOSE-1,6-BISPHOSPHATASE;
D O I：
10.1021/acs.orglett.7b02183
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
A new double functionalization reaction of alkenes through AgNO3-mediated phosphinoyl radical addition followed by Cu(II)-catalyzed amination is introduced. This one-pot, three-component reaction is performed under mild conditions to afford alpha,beta-aminophosphinoylation products.
引用
收藏
页码：4704 / 4706
页数：3
相关论文
共 50 条
  • [1] Phosphinoyl radical-initiated vicinal hydroxy-phosphorylation of alkenes
    Shoberu, Adedamola
    Li, Shuai-Shuai
    Zhang, Guo-Yu
    Li, Da-Peng
    Zou, Jian-Ping
    TETRAHEDRON, 2019, 75 (47)
  • [2] Phosphinoyl Radical-Initiated 1,2-Bifunctional Thiocyanodiphenylphosphinoylation of Alkenes
    Tao, Ze-Kun
    Li, Cheng-Kun
    Zhang, Pei-Zhi
    Shoberu, Adedamola
    Zou, Jian-Ping
    Zhang, Wei
    JOURNAL OF ORGANIC CHEMISTRY, 2018, 83 (04): : 2418 - 2424
  • [3] Phosphinoyl Radical Initiated Vicinal Cyanophosphinoylation of Alkenes
    Zhang, Pei-Zhi
    Zhang, Ling
    Li, Jian-An
    Shoberu, Adedamola
    Zou, Jian-Ping
    Zhang, Wei
    ORGANIC LETTERS, 2017, 19 (20) : 5537 - 5540
  • [4] Copper-Catalyzed Vicinal Cyano-, Thiocyano-, and Chlorophosphorylation of Alkynes: A Phosphinoyl Radical-Initiated Approach for Difunctionalized Alkenes
    Tao, Ze-Kun
    Li, Cheng-Kun
    Li, Jian-An
    Shoberu, Adedamola
    Zhang, Wei
    Zou, Jian-Ping
    ORGANIC LETTERS, 2021, 23 (11) : 4342 - 4347
  • [5] Radical-Initiated and Thermally Induced Hydrogermylation of Alkenes on the Surfaces of Germanium Nanosheets
    Yu, Haoyang
    Helbich, Tobias
    Scherf, Lavinia M.
    Chen, Jian
    Cui, Kai
    Faessler, Thomas F.
    Rieger, Bernhard
    Veinot, Jonathan G. C.
    CHEMISTRY OF MATERIALS, 2018, 30 (07) : 2274 - 2280
  • [6] Formation of β-hydroxycarbonyls from the OH radical-initiated reactions of selected alkenes
    Aschmann, SM
    Arey, J
    Atkinson, R
    ENVIRONMENTAL SCIENCE & TECHNOLOGY, 2000, 34 (09) : 1702 - 1706
  • [7] Cu/Chiral Phosphoric Acid-Catalyzed Asymmetric Radical-Initiated Aminoarylation of Alkenes
    Li Xue-Fei
    Lin Jin-Shun
    Wang Jian
    Li Zhong-Liang
    Gu Qiang-Shuai
    Liu Xin-Yuan
    ACTA CHIMICA SINICA, 2018, 76 (11) : 878 - 882
  • [8] DETERMINATION OF RADICAL YIELD IN RADICAL-INITIATED POLYMERIZATION
    MUNZER, M
    ANGEWANDTE MAKROMOLEKULARE CHEMIE, 1970, 11 : 1 - &
  • [9] Radical-initiated oxygenation of flavonols by dioxygen
    Kaizer, J
    Speier, G
    JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL, 2001, 171 (1-2) : 33 - 36
  • [10] Hydroxyl radical-initiated aging of particulate squalane
    Zhang, Bowen
    Hu, Xiaoyu
    Yao, Lei
    Wang, Mingyi
    Yang, Gan
    Lu, Yiqun
    Liu, Yiliang
    Wang, Lin
    ATMOSPHERIC ENVIRONMENT, 2020, 237
12345