Phospho sulfonic acid: a versatile and efficient solid acid catalyst for facile synthesis of bis-(4-hydroxycoumarin-3-yl) methanes under solvent-free conditions

被引:32
|
作者
Kiasat, A. R. [1 ]
Hemat-Alian, L. [1 ]
机构
[1] Shahid Chamran Univ, Dept Pure Chem, Fac Sci, Ahvaz, Iran
关键词
Bis-(4-hydroxycoumarin-3-yl) methanes; Biscoumarin; Multicomponent reaction; Solvent-free; Phospho sulfonic acid; BISCOUMARIN; DERIVATIVES; 4-HYDROXYCOUMARIN; ALDEHYDES; WATER;
D O I
10.1007/s11164-013-1239-4
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Biscoumarin derivatives are synthesized via a simple, one-pot, pseudo three-component reaction between various arylaldehydes and 4-hydroxycoumarin using phospho sulfonic acid as a reaction mediator under solvent-free neat conditions in good to excellent yields. High yields, short reaction time, easy work-up, elimination of solvents and environmentally benign milder reaction conditions are the advantages of this procedure.
引用
收藏
页码:873 / 880
页数:8
相关论文
共 50 条
  • [21] Poly(4-vinylpyridine)-supported sulfuric acid: an efficient solid acid catalyst for the synthesis of coumarin derivatives under solvent-free conditions
    Borah, Kalyan Jyoti
    Borah, Ruli
    MONATSHEFTE FUR CHEMIE, 2011, 142 (12): : 1253 - 1257
  • [22] Poly(4-vinylpyridine)-supported sulfuric acid: an efficient solid acid catalyst for the synthesis of coumarin derivatives under solvent-free conditions
    Kalyan Jyoti Borah
    Ruli Borah
    Monatshefte für Chemie - Chemical Monthly, 2011, 142 : 1253 - 1257
  • [23] TiO2 nanoparticles: an efficient heterogeneous catalyst for synthesis of bis(indolyl)methanes under solvent-free conditions
    Rahimizadeh, Mohammad
    Bakhtiarpoor, Zahra
    Eshghi, Hossein
    Pordel, Mehdi
    Rajabzadeh, Ghadir
    MONATSHEFTE FUR CHEMIE, 2009, 140 (12): : 1465 - 1469
  • [24] TiO2 nanoparticles: an efficient heterogeneous catalyst for synthesis of bis(indolyl)methanes under solvent-free conditions
    Mohammad Rahimizadeh
    Zahra Bakhtiarpoor
    Hossein Eshghi
    Mehdi Pordel
    Ghadir Rajabzadeh
    Monatshefte für Chemie - Chemical Monthly, 2009, 140 : 1465 - 1469
  • [25] An Efficient and Reusable Cobalt Nanocatalyst for the Synthesis of Bis(indolyl)methanes under Solvent-Free Conditions
    Losada, Elia
    Rajabi, Fatemeh
    Feiz, Afsaneh
    Luque, Rafael
    CURRENT ORGANIC SYNTHESIS, 2016, 13 (06) : 888 - 892
  • [26] N-Sulfonic acid poly(4-vinylpyridinum) hydrogen sulfate as a novel, efficient, and reusable solid acid catalyst for acylation under solvent-free conditions
    Khaligh, Nader Ghaffari
    Ghasem-Abadi, Parisa Ghods
    CHINESE JOURNAL OF CATALYSIS, 2014, 35 (07) : 1126 - 1135
  • [27] Magnetic nanoparticles tris(hydrogensulfato) boron as an efficient heterogeneous acid catalyst for the synthesis of α,α-benzylidene bis(4-hydroxycoumarin) derivatives under solvent-free condition
    Hayati, Payam
    Eghbali, Khadijeh
    Rezaei, Ramin
    RESEARCH ON CHEMICAL INTERMEDIATES, 2019, 45 (10) : 5067 - 5089
  • [28] Magnetic nanoparticles tris(hydrogensulfato) boron as an efficient heterogeneous acid catalyst for the synthesis of α,ά-benzylidene bis(4-hydroxycoumarin) derivatives under solvent-free condition
    Payam Hayati
    Khadijeh Eghbali
    Ramin Rezaei
    Research on Chemical Intermediates, 2019, 45 : 5067 - 5089
  • [29] EFFICIENT SYNTHESIS OF BIS-(4-HYDROXYCOUMARIN) USING SULFANILIC ACID AS RECYCLABLE CATALYST IN WATER
    Sadat-Jalali, Mozhgan
    Manafi, Mohammadreza
    Homami, Seyed Saied
    Gorji, Banafsheh
    Monzavi, Amirhossein
    REVUE ROUMAINE DE CHIMIE, 2020, 65 (05) : 473 - 480
  • [30] Ionic liquid tributyl (carboxymethyl) phosphonium bromide as an efficient catalyst for the synthesis of bis(indolyl)methanes under solvent-free conditions
    Khazaei, Ardeshir
    Zolfigol, Mohammad Ali
    Faal-Rastegar, Toktam
    JOURNAL OF CHEMICAL RESEARCH, 2013, (10) : 617 - 619