Trichlorido-1κ2Cl,2κCl-(2,6-dimethylphenolato-2κO)-μ-oxido-bis{1,2(η5)-2,3,4,5-tetramethyl-1-[4-(trimethylsilyl)phenyl]cyclopentadienyl}dititanium(IV)

被引:1
|
作者
Luo, Xuyang [2 ]
Wu, Qiaolin [1 ]
Mu, Ying [1 ]
机构
[1] Jilin Univ, State Key Lab Supramol Struct & Mat, Sch Chem, Changchun 130012, Peoples R China
[2] Jilin Univ, Sch Chem, Changchun 130012, Peoples R China
基金
中国国家自然科学基金;
关键词
CRYSTAL-STRUCTURE; COMPLEXES;
D O I
10.1107/S1600536811035306
中图分类号
O7 [晶体学];
学科分类号
0702 ; 070205 ; 0703 ; 080501 ;
摘要
The title dinuclear titanocene, [Ti-2(C8H9O)(C18H25Si)(2)Cl3O], contains one Ti atom tetrahedrally coordinated by two Cl atoms, a bridging O atom and the substituted cyclopentadienyl ligand, and another Ti atom tetrahedrally coordinated by a Cl atom, a bridging O atom, the 2,6-dimethylphenolate ligand and the substituted cyclopentadienyl ligand. The bridging O atom lies on a twofold rotation axis.
引用
收藏
页码:M1355 / U504
页数:14
相关论文
共 50 条
  • [21] Trichlorido{2-[2-(η5-cyclopentadienyl)-2-methylpropyl]-1-trimethylsilyl-1H-imidazole-κN3}titanium(IV) tetrahydrofuran hemisolvate
    Ge, Fang
    Nie, Wanli
    Borzov, Maxim V.
    Churakov, Andrei V.
    ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE, 2010, 66 : M546 - U722
  • [22] Crystal structure of poly[(di-μ2-aqua-κ2O:O)bis(μ5-oxalato-1:2κ2O1; 1κ1O2; 3:4:5κ3O3; 3κ1O4)(μ4-oxalato-1:2κ2O1; 2:3κ2O2; 3:4κ2O3; 4:1κ2O4)dizinc(II)disodium(I)]
    Zhou, Fang-Xia
    ZEITSCHRIFT FUR KRISTALLOGRAPHIE-NEW CRYSTAL STRUCTURES, 2016, 231 (01): : 225 - 226
  • [23] Decaaqua-1κ5O,4κ5O-bis(μ-nitrilotriacetate)-1:2κ5O:N,O′,O",O′";3:4κ5N,O,O′,O":O′"-μ-oxido-2:3κ2O:O-diperoxido-2κ2O,O′;3κ2O,O′-1,4-dicopper(II)-2,3-dititanium(IV) heptahydrate
    Xie, Xiao-Hua
    Wang, Bai-Mu
    Ng, Seik Weng
    ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE, 2010, 66 : M271 - U3287
  • [24] Pentacarbonyl-2κ5 C-chlorido-1κCl-bis[1(η5)-cyclopentadienyl](μ-a- oxidobenzylidene-1:2κ2O:C)titanium(IV)-tungsten(0)
    Esterhuysen, Catharine
    Nel, I. B. Jacques
    Esterhuysen, Matthias W.
    Cronje, Stephanie
    ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE, 2008, 64 : M1534 - U513
  • [25] Crystal structures of two CuII compounds: catena-poly[[chloridocopper(II)]-μ-N-[ethoxy(pyridin-2-yl)methylidene]-N′-[oxido(pyridin-3-yl)methylidene]hydrazine-κ4N,N′,O:N"] and di-μ-chlorido-1:4κ2Cl:Cl-2:3κ2Cl:Cl-dichlorido-2κCl,4κCl-bis-[μ3-ethoxy(pyridin-2-yl)methanolato-1:2:3κ3O:-N,O:O;1 :3:4κ3O:O:N,O]bis[μ2-ethoxy(pyridin-2-yl)methanolato-1:2κ3N,O:O;3:4κ3N,O:O]tetra-copper(II)
    Sall, Ousmane
    Tamboura, Farba Bouyagui
    Sy, Adama
    Barry, Aliou Hamady
    Thiam, Elhadj Ibrahima
    Gaye, Mohamed
    Ellena, Javier
    ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS, 2019, 75 : 1069 - +
  • [26] RRKM CALCULATED UNIMOLECULAR REACTION RATES FOR CHEMICALLY AND THERMALLY ACTIVATED C2H5CL 1,1-C2H4CL2 AND 1,2-C2H4CL2
    HASSLER, JC
    SETSER, DW
    JOURNAL OF CHEMICAL PHYSICS, 1966, 45 (09): : 3246 - +
  • [27] CHLORINE-PHOTOSENSITIZED REACTIONS IN CL2+O2+1,1,1,2-C2H2CL4 SYSTEM
    GILLOTAY, D
    OLBREGTS, J
    INTERNATIONAL JOURNAL OF CHEMICAL KINETICS, 1976, 8 (01) : 11 - 22
  • [28] Bis[bis(trimethylsilyl)cyclopentadienyl]selane as a ligand:: selena-2,2′,4,4′-tetrakis(trimethylsilyl)-[1]ferrocenophane and 1,2,3-triselena-2,2′,4,4′-tetrakis(trimethylsilyl)-[3]ferrocenophane
    Thaler, G
    Klotz, B
    Wurst, K
    Sladky, F
    JOURNAL OF ORGANOMETALLIC CHEMISTRY, 2001, 637 : 745 - 750
  • [29] Octa-n-butyl-1κ2C,2κ2C,3κ2,4κ2C-bis(μ-2,3-dibromopropionato)-1:2κ2O:O′,3:4κ2O:O′-bis(2,3-dibromopropionato)-1κO,3κO-di-μ3-oxido-1:2:4κ3O:O:O,2:3:4κ3O:O:O-tetratin(IV)
    Win, Yip Foo
    Teoh, Siang Guan
    Ha, Sie Tiong
    Kia, Reza
    Fun, Hoong-Kun
    ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE, 2008, 64 : M1572 - U869
  • [30] The crystal structure of the cocrystal di-μ2-chlorido-octamethyl-di-μ3-oxido-bis(2,3,4,5-tetrafluorobenzoato-κ2O,O′)tetratin(IV)-octamethyl-di-μ3-oxido-bis(μ2-2,3,4,5-tetrafluorobenzoato-κ2O:O′)-bis(μ2-2,3,4,5-tetrafluorobenzoato-κ2O:O;O′)tetratin(IV) C58H54Cl2F24O16Sn8
    Sun, Junshan
    ZEITSCHRIFT FUR KRISTALLOGRAPHIE-NEW CRYSTAL STRUCTURES, 2021, 236 (06): : 1231 - 1233