Electrofluorination of olefins substituted electron-withdrawing group.

被引：0
|
作者：
Baroux, P
Tardivel, R
Simonet, J
机构：
来源：
PROCEEDINGS OF THE SYMPOSIUM ON ELECTROCHEMISTRY IN THE PREPARATION OF FLUORINE AND ITS COMPOUNDS | 1997年 / 97卷 / 15期
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中图分类号：
O646 [电化学、电解、磁化学];
学科分类号：
081704 ;
摘要：
The electrochemical oxidation of electron-poor enol ethers and olefins conducted in CH3CN/Et3N.3HF at platinum anode mainly results in fluoroacetamidation and difluorination. These reactions are regiospecific (case of monofluorination) and seem to be stereoselective even if definitive attributions of three and erythro isomers (case of difluorinated compounds and fluoroacetamide) were not yet definitively established.
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页码：91 / 100
页数：10
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