Acetophenone hydrogenation over a Pd catalyst in the presence of H2O and CO2

被引：35
|
作者：
Hiyoshi, Norihito [1 ]
Sato, Osamu [1 ]
Yamaguchi, Aritomo [1 ]
Shirai, Masayuki [1 ]
机构：
[1] Natl Inst Adv Ind Sci & Technol, Res Ctr Compact Chem Syst, Miyagino Ku, Sendai, Miyagi 9838551, Japan
来源：
CHEMICAL COMMUNICATIONS | 2011年 / 47卷 / 41期
关键词：
TEMPERATURE LIQUID WATER; CARBON-DIOXIDE; SOLUBILITY; ACID; PRESSURE; ALCOHOLS;
D O I：
10.1039/c1cc13130c
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
The addition of carbon dioxide and water enhances acetophenone hydrogenation activity over an activated carbon-supported palladium catalyst, and 1-phenylethanol can be easily recovered without distillation and neutralization. Two liquid phases (water and acetophenone) are indispensable for enhancement of the hydrogenation rate.
引用
收藏
页码：11546 / 11548
页数：3
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