pH/temperature dependent phase transition of an interpenetrating polymer network: Anomalous swelling behavior above lower critical solution temperature

被引：43
|
作者：
Shin, BC
Jhon, MS [1 ]
Lee, HB
Yuk, SH
机构：
[1] Korea Adv Inst Sci & Technol, Ctr Mol Sci, Taejon 305343, South Korea
[2] Korea Adv Inst Sci & Technol, Dept Chem, Taejon 305343, South Korea
[3] Korea Res Inst Chem Technol, Biomat Lab, Taejon 305343, South Korea
来源：
EUROPEAN POLYMER JOURNAL | 1998年 / 34卷 / 11期
关键词：
D O I：
10.1016/S0014-3057(98)00025-1
中图分类号：
O63 [高分子化学（高聚物）];
学科分类号：
070305 ; 080501 ; 081704 ;
摘要：
Anomalous swelling behavior has been observed in interpenetrating polymer networks (IPNs) gel composed of poly (N-isopropylacrylamide) (PNIPAIM) and poly(acrylic acid) (PAA). Calorimetric endotherms, FT-IR (Fourier transform-infrared) spectra and compression modulus show that the molecular interaction such as hydrogen bond and hydrophobic interaction serve-as a driving force which takes place with an anomalous swelling behavior. (C) 1998 Elsevier Science Ltd. All rights reserved.
引用
收藏
页码：1675 / 1681
页数：7
相关论文
共 50 条
  • [31] PHASE-SEPARATION IN A MICELLAR SOLUTION OF A BLOCK CO-POLYMER IN THE REGION OF A LOWER CRITICAL SOLUTION TEMPERATURE
    PRICE, C
    KENDALL, KD
    STUBBERSFIELD, RB
    WRIGHT, B
    POLYMER COMMUNICATIONS, 1983, 24 (07): : 200 - 202
  • [32] Competitive swelling forces and interpolymer complexation in pH- and temperature-sensitive interpenetrating network hydrogels
    Kelmanovich, Shira G.
    Parke-Houben, Rachel
    Frank, Curtis W.
    SOFT MATTER, 2012, 8 (31) : 8137 - 8148
  • [33] Liquid–liquid phase separation of N-isopropylpropionamide aqueous solutions above the lower critical solution temperature
    Kenji Mochizuki
    Tomonari Sumi
    Kenichiro Koga
    Scientific Reports, 6
  • [34] DIFFUSION OF GASES IN POLYMER BLENDS NEAR THE LOWER CRITICAL SOLUTION TEMPERATURE
    LI, RJ
    KWEI, TK
    MYERSON, AS
    AICHE JOURNAL, 1995, 41 (01) : 166 - 170
  • [35] Miscibility determination of a lower critical solution temperature polymer blend by rheology
    Sharma, J
    Clarke, N
    JOURNAL OF PHYSICAL CHEMISTRY B, 2004, 108 (35): : 13220 - 13230
  • [36] Unusual Lower Critical Solution Temperature Phase Behavior of Poly(ethylene oxide) in Ionic Liquids
    Lee, Hau-Nan
    Newell, Nakisha
    Bai, Zhifeng
    Lodge, Timothy P.
    MACROMOLECULES, 2012, 45 (08) : 3627 - 3633
  • [37] Lower Critical Solution Temperature (LCST) Phase Behavior of Poly(ethylene oxide) in Ionic Liquids
    Lee, Hau-Nan
    Lodge, Timothy P.
    JOURNAL OF PHYSICAL CHEMISTRY LETTERS, 2010, 1 (13): : 1962 - 1966
  • [38] Modeling lower critical solution temperature behavior of associating polymer brushes with classical density functional theory
    Gong, Kai
    Marshall, Bennett D.
    Chapman, Walter G.
    JOURNAL OF CHEMICAL PHYSICS, 2013, 139 (09):
  • [39] Circulatory osmotic desalination driven by a mild temperature gradient based on lower critical solution temperature (LCST) phase transition materials
    Mok, Yeongbong
    Nakayama, Daichi
    Noh, Minwoo
    Jang, Sangmok
    Kim, Taeho
    Lee, Yan
    PHYSICAL CHEMISTRY CHEMICAL PHYSICS, 2013, 15 (44) : 19510 - 19517
  • [40] PRESSURE EFFECTS IN POLYMER-SOLUTION PHASE EQUILIBRIA .1. LOWER CRITICAL SOLUTION TEMPERATURE OF POLYISOBUTYLENE AND POLYDIMETHYLSILOXANE OR LOWER ALKANES
    ZEMAN, L
    DELMAS, G
    BIROS, J
    PATTERSO.D
    JOURNAL OF PHYSICAL CHEMISTRY, 1972, 76 (08): : 1206 - &
12345