Synthesis and Structural Studies of Organotin(IV) and Organolead(IV) Thiophene-2-thiocarboxylate

被引：18

作者：

Singh, Suryabhan ^{[1
]}

Bhattacharya, Subrato ^{[1
]}

Noeth, Heinrich ^{[2
]}

机构：

[1] Banaras Hindu Univ, Fac Sci, Dept Chem, Varanasi 221005, Uttar Pradesh, India

[2] Univ Munich, Dept Chem, D-81377 Munich, Germany

来源：

EUROPEAN JOURNAL OF INORGANIC CHEMISTRY | 2010年 / 36期

关键词：

Tin; Lead; Thiocarboxylate; Thiophene; Density functional calculations; Structure elucidation; EFFECTIVE CORE POTENTIALS; MOLECULAR CALCULATIONS; CRYSTAL-STRUCTURES; INITIO; COMPLEXES; SN; DERIVATIVES; CHEMISTRY; SOLUTES; ACID;

D O I：

10.1002/ejic.201000692

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

A few organotin(IV) ([R2SnCl2], [R3SnCl]; R = Me, Ph, nPr, or nBu) and organolead(IV) ([Ph2PbCl2], [Ph3PbCl]) compounds that contain the thiophene-2-thiocarboxylate ligand have been synthesized and characterized by H-1, C-13, Sn-119 NMR; FTIR; and UV/Vis spectroscopy. The molecular structures of some of the compounds were studied by single-crystal X-ray diffraction. Structures and electronic transitions have been explained on the basis of DFT calculations.

引用

页码：5691 / 5699

页数：9

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