Rh(III)-Catalyzed Tandem Oxidative Olefination-Michael Reactions between Aryl Carboxamides and Alkenes

被引：264
|
作者：
Wang, Fen [1 ]
Song, Guoyong [1 ]
Li, Xingwei [1 ]
机构：
[1] Chinese Acad Sci, Dalian Inst Chem Phys, Dalian 116023, Peoples R China
来源：
ORGANIC LETTERS | 2010年 / 12卷 / 23期
关键词：
C-H BOND; INTERNAL ALKYNES; ROOM-TEMPERATURE; BENZOIC-ACIDS; ACTIVATION; FUNCTIONALIZATION; ARYLATION; INDOLES; COUPLING/CYCLIZATION; ALKYLATION;
D O I：
10.1021/ol102241f
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
Rh(III)-catalyzed oxidative coupling reactions between benzamides or heteroaryl carboxamides and olefins have been developed. The vinylation product can further undergo a Michael reaction leading to gamma-lactam in the case of electron-withdrawing olefins.
引用
收藏
页码：5430 / 5433
页数：4
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