SERS active Ag-SiO2 nanoparticles obtained by laser ablation of silver in colloidal silica

被引:11
|
作者
Gellini, Cristina [1 ]
Muniz-Miranda, Francesco [2 ,3 ]
Pedone, Alfonso [2 ]
Muniz-Miranda, Maurizio [1 ]
机构
[1] Univ Florence, Dept Chem Ugo Schiff, Via Lastruccia 3, I-50019 Sesto Fiorentino, Italy
[2] Univ Modena & Reggio Emilia, Dept Chem & Geol Sci, Via Campi 103, I-41125 Modena, Italy
[3] Univ Ghent, Ctr Mol Modeling, Technol Pk 903, B-9052 Zwijnaarde, Belgium
来源
关键词
2,2 '-bipyridine; DFT; laser ablation; silica; silver; ENHANCED RAMAN-SCATTERING; EFFECTIVE CORE POTENTIALS; MOLECULAR CALCULATIONS; AG-AT-SIO2; NANOPARTICLES; DOPED SILICA; THIN-FILMS; SURFACE; IONS; AU-AT-SIO2; MECHANISM;
D O I
10.3762/bjnano.9.224
中图分类号
TB3 [工程材料学];
学科分类号
0805 ; 080502 ;
摘要
Highly stable Ag-SiO2 nanoparticle composites were first obtained by laser ablation of a silver target in an aqueous colloidal dispersion of silica and examined by UV-vis absorption spectroscopy, transmission electron microscopy and Raman spectroscopy. The surface enhanced Raman scattering (SERS) activity of these nanocomposites was tested using 2,2'-bipyridine as a molecular reporter and excitation in the visible and near-IR spectral regions. The computational DFT approach provided evidence of ligand adsorption on positively charged adatoms of the silver nanostructured surface, in a very similar way to the metal/molecule interaction occurring in the corresponding Ag(I) coordination compound.
引用
收藏
页码:2396 / 2404
页数:9
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