Optical micro-lens array for laser plasma generation in spectrochemical analysis

被引:8
|
作者
Sturm, Volker [1 ]
机构
[1] Fraunhofer Inst Lasertechn ILT, D-52074 Aachen, Germany
关键词
D O I
10.1039/b708564h
中图分类号
O65 [分析化学];
学科分类号
070302 ; 081704 ;
摘要
A Q- switched Nd: YAG laser beam is focused by an optical micro- lens array to produce a laser plasma at a target. The spatial intensity distribution in the focal plane is an array of closely-spaced high intensity spots. At a laser output energy of similar to 200 mJ ( wavelength 1064 nm, pulse duration similar to 8 ns, repetition rate 10 Hz), a laser- induced air breakdown is observed in similar to 47 spots inside an area of similar to 9 mm diameter at the focal plane. For solid targets, a laser plasma is produced with a micro- lens array for spectrochemical analysis, e. g., laser- induced breakdown spectroscopy. Emission spectra of the laser plasma plume as well as pulse- to- pulse measurements with a simultaneous spectrometer are taken from a rotating slag sample with inhomogeneous distribution of species such as SiO2 or CaO. For the micro- lens configuration, the variation of the spectral line emission, e. g., of Si and Ca lines, is reduced in comparison with a single lens focusing showing the averaging effect of the micro- lens array produced plasma. A more representative analysis of the average concentration of inhomogeneous samples can be expected without elaborate and time- consuming sequential scanning of extended sample areas. Calibration curves for SiO2 and Fe2O3 are taken with samples of silicate glasses.
引用
收藏
页码:1495 / 1500
页数:6
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