Structural, chemical and physical properties of pure and La3+ doped L-Threonine acetate crystals

被引:4
|
作者
Senthamizhan, A. [1 ]
Sambathkumar, K. [2 ]
Nithiyanantham, S. [3 ,4 ,5 ]
Venkatachalapathy, M. [6 ]
Rajkamal, N. [6 ]
机构
[1] VRS Coll Engn & Technol, Dept Phys, Villupuram 605602, Tamil Nadu, India
[2] AA Govt Arts Coll, Dept Phys, Villupuram 605602, Tamil Nadu, India
[3] Thiru Vi Kalyanansundaram Govt Arts & Sci Coll, Dept Phys, Magnetism & Magnet Mat Div, Thiruvarur 610003, India
[4] Thiru Vi Kalyanansundaram Govt Arts & Sci Coll, Dept Phys, Thin Film Div, Thiruvarur 610003, India
[5] Bharathidasan Univ, Tiruchirappalli, India
[6] TAG Govt Arts Coll, Dept Phys, Tindivanam 602001, Tamil Nadu, India
关键词
Single crystal; Spectroscopic studies; Structure; Optical; NLO; Micro hardness; NONLINEAR-OPTICAL CRYSTAL; GROWTH; THIOCYANATE;
D O I
10.1016/j.molstruc.2017.08.012
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
The pure and La3+ doped L-Threonine crystals can be grown by slow evaporation techniques. The crystal structure were examined through X-Ray diffraction (XRD) analysis, confirmed the P2(1)2(1)2(1) system. The quantitative nature of dopant can be analyzed with Inductively Coupled Plasma (ICP) study. The Fourier Transform Infra-Red (FTIR) and Fourier Transform (FT- Raman) investigations yields the possible stretching/bonding with their functional groups and the qualitative/quantitative nature of both crystals is analyzed. The optical behavior of crystals can be studied through Ultra Violet (UV)- Visible spectrometer. The mechanical, thermal and decomposition studies can be carried out through Vickers hardness test, Thermo Gravometric Analysis (TGA) and Differential Thermal Analysis (DTA). The Non Linear Optical (NLO) properties are found more than Potassium Phosphate (KDP) through Kurtz powders technique. The dielectric and optical absorption studies for both pure and L-doped crystals were studied and interpreted all the properties. The La3+ dopant increases the properties are investigated. (C) 2017 Elsevier B.V. All rights reserved.
引用
收藏
页码:373 / 378
页数:6
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