Guest encapsulation within self-assembled molecular containers

被引：74

作者：

Schmuck, Carsten ^{[1
]}

机构：

[1] Univ Wurzburg, Inst Organ Chem, D-97074 Wurzburg, Germany

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2007年 / 46卷 / 31期

关键词：

encapsulation; host-guest systems; self-assembly; supramolecular chemistry; BOWL-SHAPED HOST; CRYSTALLOGRAPHIC OBSERVATION; BINDING-PROPERTIES; DIELS-ALDER; WATER; CAPSULES; HEMICARCERAND; RECOGNITION; STABILIZATION; CATALYSIS;

D O I：

10.1002/anie.200702125

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Molecular hospitality: Self-assembled molecular containers provide a very specific geometric as well as chemical environment for a bound guest, which allows for selective guest binding or the stabilization of unstable molecules or unstable conformations within the capsule (see scheme). The geometric constraints imposed by the container can even change the outcome of a chemical reaction. (Figure Presented). © 2007 Wiley-VCH Verlag GmbH & Co. KGaA.

引用

页码：5830 / 5833

页数：4

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