Poly[ethylenediammonium [cuprate(II)-μ4-benzene-1,2,4,5-tetracarboxylato-κ4O:O′:O":O"′] 2.5-hydrate]

被引:3
|
作者
Rafizadeh, Masoud
Amani, Vahid
Dehghan, Leila
Azadbakht, Fatemeh
Sahlolbei, Elham
机构
[1] Acad Sci Studies Educ, Tehran, Iran
[2] Teacher Training Univ, Dept Chem, Tehran 15614, Iran
关键词
D O I
10.1107/S1600536807025834
中图分类号
O7 [晶体学];
学科分类号
0702 ; 070205 ; 0703 ; 080501 ;
摘要
The asymmetric unit of the title compound, {( C2H10N2)[ Cu( C(10H)2O(8))] center dot 2.5H(2)O} (n), contains one cuprate( II)- mu (4)benzene- 1,2,4,5- tetracarboxylate anion, one ethylenediammonium cation and two and a half water molecules. The Cu atom is four- coordinated by four O atoms from four benzene- 1,2,4,5- tetracarboxylate anions. Intra- and intermolecular O - H center dot center dot center dot O and N - H center dot center dot center dot O hydrogen bonds in the formation of a supramolecular structure. One of the water molecules is disordered equally over two sites.
引用
收藏
页码:M1841 / U599
页数:12
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