Crystal structures of N,N′-(m-tolyl)thiourea and N,N′-(p-tolyl)thiourea

被引：5
|
作者：
Soriano-Garcia, M
Chavez, GT
Cedillo, FD
Perez, AED
Hernandez, GA
机构：
[1] Univ Nacl Autonoma Mexico, Dept Bioestructura, Inst Quim, Mexico City 04510, DF, Mexico
[2] Escuela Nacl Ciencias Biol, Dept Quim Organ, IPN Prolongac Carpio & Plan Ayala, Mexico City 11340, DF, Mexico
[3] Univ Nacl Autonoma Mexico, Dept Quim Inorgan & Nucl, Fac Quim, Mexico City 04510, DF, Mexico
[4] Inst Technol Tijuana, Ctr Graduados & Invest, Baja California, Mexico
来源：
ANALYTICAL SCIENCES | 2003年 / 19卷 / 07期
关键词：
D O I：
10.2116/analsci.19.1087
中图分类号：
O65 [分析化学];
学科分类号：
070302 ; 081704 ;
摘要：
C(15)H(16)N(2)S is monoclinic [orthorhombic], P2(1)/c [Pbcn]. Unit-cell dimensions at 293 K are a = 9.506(1), b = 7.629(1), c = 20.077(1)Angstrom, beta = 99.93(1)degrees, V = 1434.2(2)Angstrom(3), D(x) = 1.187 g/cm(3), and Z = 4 [a = 11.806(2), b = 13.954(2), c = 8.466(1)Angstrom, V = 1394.7(3)Angstrom(3), D(x) = 1.221 g/cm(3), and Z = 8]. The R value is 0.049 [0.045] for 1620 [1229] observed reflections. The dihedral angle between the tolyl rings is 53.6(1)degrees [47.9(1)degrees]. The crystal structures are stabilized by N-H...S hydrogen bonds and van der Waals forces.
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收藏
页码：1087 / 1088
页数：2
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